Electrochemical Alkoxylation of Benzylic C(sp3)−H Bonds

Abstract We report an electrochemical process for the direct alkoxylation of benzylic C(sp 3 )−H bonds without the need for external oxidants or metal catalysts. This environmentally friendly and sustainable synthetic strategy facilitates the alkoxylation of C(sp 3 )−H in benzylic groups. The approach enables the late‐stage incorporation of complex alkoxy groups into bioactive molecules, providing potential applications in the synthesis of celestolide derivatives.