In this paper, the principle and the research method of organic electrosynthesis-one of the most efficient technology is discussed. Compared to the traditional organic synthesis, the advantages of organic electrosynthesis lies in that it can get rid of the source of pollution. This article also demonstrate the importance and the latest application domain of electrosynthesis technique in the course of realizing green chemical industry according to some industrial applications in China.In the 21th century, chemistry theory and application will focus on the organic electrosynthesis.