材料科学
锂(药物)
阳极
电池(电)
化学工程
锂离子电池
储能
离子
法拉第效率
电化学
电解质
无机化学
作者
Jianhua Yang,F. Mo,L. Huang,H. Liang,G. Sun,S. Peng
标识
DOI:10.1016/j.mtener.2021.100662
摘要
Abstract Black phosphorus/natural graphene (BP/NG) composite electrode material for all-solid-state lithium-ion batteries (ASSLIBs) was fabricated by a facile ball milling method. A C-P bond with characteristics of high ion and electron transfer was constructed, which unlocked the reversible cycling and rate performance of phosphorus. In addition, compounding black phosphorus (BP) with natural graphene (NG) can relieve the large internal stress caused by volume change during cycling and improve the stability of the long cycling and high-rate performance. At current density of 0.5 A g−1, a high specific capacity of 750 mAh g−1 remained after 100 cycles, whereas at high current density of 1 A g−1 , the BP/NG anode material delivered a reversible capacity of ~300 mAh g −1. Furthermore, the reaction controlling step of LixP delithiation was revealed by kinetic measurement. In addition, when coupling BP/NG anode material with TiS2 to assemble a full solid-state cell, it delivered a high capacity of 400 mAh g−1 after 30 cycles, indicating a potential of further application. This work expanded the candidate of anode materials for ASSLIBs and provided aid for the further application of all-solid-state batteries.
科研通智能强力驱动
Strongly Powered by AbleSci AI