In this study, cellulosemethacrylate was firstly prepared by the reaction of methacryloyl chloride withprimary OH groups on raw cellulose. The graft copolymerization of cellulose wasmade with our own synthesized 2-(4-Methoxyphenylamino)-2-oxoethyl methacrylate(MPAEMA) monomer by method of free radical polymerization. Cellulose, cellulosemethacrylate and its graft copolymer (Cell.met-g-MPAEMA) were characterized by FT-IRspectra, elemental and thermal analysis.