材料科学
阳极
纳米棒
纳米颗粒
化学工程
碳纳米管
储能
碳纤维
纳米技术
电极
涂层
兴奋剂
复合数
多孔性
阴极
复合材料
光电子学
化学
物理化学
工程类
功率(物理)
物理
量子力学
作者
Jian Feng,Shaohua Luo,Yi-cheng Lin,Zhan Yang,Shengxue Yan,Pengqing Hou,Qing Wang,Yahui Zhang
标识
DOI:10.1016/j.jpowsour.2022.231444
摘要
Engineering ideal anode materials with low cost, considerable reaction kinetics and good structural stability are urgently needed for sodium-ion batteries (SIBs) toward large-scale applications. Here, a hierarchical peapod-like nanorod consisting of CoSe2/N-doped carbon (NC) core-shell nanoparticles (NPs) embedded into one-dimensional (1D) N-doped carbon nanotubes (CoSe2/[email protected]) with inner void space is developed and fabricated by a self-template, dopamine-coating, and succeeding selenization strategy. In the cleverly designed CoSe2/[email protected] composite, the 1D peapod-like structure provides high mechanical strength and allows for fast mass transport/electron transfer. The external NCNTs and inner void space can effectively accommodate volumetric undulation and restrain the aggregation of CoSe2 NPs. Based on these advantages, the CoSe2/[email protected] electrode exhibits excellent comprehensive sodium storage performance, e.g., good rate capability (386.3 mAh g−1 at 10.0 A g−1) and high cycling stability (394.2 mAh g−1 up to 4500 loops at 5.0 A g−1). Moreover, the SIB full cells (Na3V2(PO4)3@C cathodes vs CoSe2/[email protected] anodes) can achieve a reversible capacity of 75.6 mAh g−1total after 200 cycles at 0.5 A g−1. This work provides a feasible avenue to construct stable energy-storage materials.
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