Heterogenization of Molecular Water Oxidation Catalysts in Electrodes for (Photo)Electrochemical Water Oxidation

Water oxidation is still one of the most important challenges to develop efficient artificial photosynthetic devices. In recent decades, the development and study of molecular complexes for water oxidation have allowed insight into the principles governing catalytic activity and the mechanism as well as establish ligand design guidelines to improve performance. However, their durability and long-term stability compromise the performance of molecular-based artificial photosynthetic devices. In this context, heterogenization of molecular water oxidation catalysts on electrode surfaces has emerged as a promising approach for efficient long-lasting water oxidation for artificial photosynthetic devices. This review covers the state of the art of strategies for the heterogenization of molecular water oxidation catalysts onto electrodes for (photo)electrochemical water oxidation. An overview and description of the main binding strategies are provided explaining the advantages of each strategy and their scope. Moreover, selected examples are discussed together with the the differences in activity and stability between the homogeneous and the heterogenized system when reported. Finally, the common design principles for efficient (photo)electrocatalytic performance summarized.