材料科学
电解质
电池(电)
阴极
复合数
陶瓷
离子电导率
膜
锂(药物)
聚合物
化学工程
锂电池
阳极
复合材料
快离子导体
电极
离子键合
电气工程
离子
有机化学
化学
功率(物理)
内分泌学
工程类
物理化学
物理
医学
量子力学
生物化学
作者
Wenqiang Zhang,Jinhui Nie,Li Fan,Zhong Lin Wang,Chunwen Sun
出处
期刊:Nano Energy
[Elsevier]
日期:2018-03-01
卷期号:45: 413-419
被引量:473
标识
DOI:10.1016/j.nanoen.2018.01.028
摘要
Polymer–ceramic composite electrolytes are emerging as a promising solution to achieving high ionic conductivity, optimal mechanical properties, and good safety for developing high-performance all-solid-state rechargeable batteries. In this work, we report a garnet (Li7La3Zr2O12)-based hybrid solid electrolyte (HSE) membrane designed for high performance solid-state lithium batteries for the first time. The composite HSE membrane is composed of LLZO particles and PVDF–HFP polymer matrix. The solid-state lithium battery with this HSE membrane, Li metal anode and LiFePO4 cathode exhibits an initial reversible discharge capacity of 120 mA h g−1 at a charge/discharge current density of 0.5 C at room temperature. This solid-state battery is used to store the energy harvested by a TENG at different rotation rates. The solid state battery can efficiently store the pulsed energy, especially for output at high frequencies.
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