Polyvinyl alcohol flame retardant film based on halloysite nanotubes, chitosan and phytic acid with strong mechanical and anti-ultraviolet properties

The research of additive biomass flame retardants is becoming more and more popular. In this work, amino modified halloysite nanotubes (A-HNTs), chitosan (CS) and phytic acid (PA) were introduced into polyvinyl alcohol (PVA) matrix to construct PA/A-HNT/CS/PVA organic-inorganic composite film with hydrogen bond and covalent bond cross-linking network structure. Adding PA/A-HNT/CS can remarkably improve the mechanical strength, UV resistance and thermal stability of PVA film. Compared with control PVA film, the transmittance of composite film in ultraviolet region decreases from 90 % to <15 %, and the tensile strength raises from 19.8 MPa to 31.0 MPa. The thermal decomposition temperature of the composite film increases, the weight loss rate decreases obviously, and the carbon residue can reach 26 wt% at 700 °C. The limiting oxygen index increases from 18.5 % to 32.2 %. Furthermore, the addition of this flame-retardant system can obviously reduce the combustion intensity of PVA, and its flame-retardant grade can reach V-0. It is of great significance to expand the application of PVA and the development of biomass flame retardant.