Magnetic Interactions Versus Magnetic Anisotropy in Spinel Ferrite Nanoparticles

We investigated the flexibility of high-temperature thermal decomposition synthesis to design magnetic \nnanoparticles (NPs) with engineered properties. We prepared spinel iron oxide particles with the desired composition \n(Fe3O4 and CoFe2O4) and a well-controlled average size (5−8 nm) by tuning the synthesis procedure. The substitution of \nFe by Co produces a dramatic increase of the magnetocrystalline anisotropy: for 5 nm particles, the anisotropy constant \nincreased from ∼3.9×104 to ∼7.5×105 J/m3. The magnetocrystalline anisotropy has shown a major effect on the magnetic \nbehavior of highly crystalline particles, except for the smallest iron oxide sample, where the surface anisotropy plays a \ndominant role. The presence of surfactant (oleic acid) on the NPs surface prevents direct exchange coupling among them, \nwhereas the dipolar interaction was predominant, with an estimated temperature-equivalent energy in the range of 4−60 K.