材料科学
聚合物
锂(药物)
聚合
电化学
纳米颗粒
电极
化学工程
阴极
降水
电解质
沉淀聚合
纳米技术
自由基聚合
复合材料
物理
工程类
内分泌学
物理化学
气象学
化学
医学
作者
Yeqing Shi,Jiangrong Yang,Jixing Yang,Zhuanping Wang,Zifeng Chen,Yunhua Xu
标识
DOI:10.1002/adfm.202111307
摘要
Abstract Polymer electrode materials are often poorly soluble in liquid organic electrolytes of lithium‐ion batteries, yet they suffer from issues of severe agglomeration and complicated synthesis processes, which hinder their practical applications. Herein, spherical cross‐linked quinone‐amine polymer nanoparticles (denoted as PQANPs) are synthesized through a facile precipitation polymerization, which can effectively address the agglomeration problems of polymer electrode materials. The cross‐linking degrees of polymers and diameters of PQANPs can be facilely tuned by adjusting the feed ratios of p ‐benzoquinone to 3,3′‐diaminobenzidine. The optimized PQANP demonstrates excellent electrochemical performance with an ultrafast rate capability of 25 A g −1 and an ultralong cycle life of 20 000 cycles, which exceed all benzoquinone‐based polymer electrode materials reported in the literature. The findings offer an efficient and convenient strategy for high‐performance nanostructured polymer electrode materials.
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