Zn(ii) and Cd(ii) coordination polymers with a new angular bis-pyridyl-bis-amide: synthesis, structures and sensing properties

Zn(ii) and Cd(ii) coordination polymers that show a 2D double layer with the rare (4⁶·6⁴)-5 L4 topology and a 3D framework with a new (4·5·6)(4⁵·5⁵·6⁹·7·8) topology, respectively, show good selectivity toward the detection of Fe³⁺ ions.