Electrospun Nanofibers with Antibacterial and Antioxidant Activities for Air Purification

纳米纤维 抗菌活性 抗氧化剂 空气净化 静电纺丝 化学 抗菌肽 纳米技术 材料科学 工程类 生物化学 有机化学 生物 细菌 机械工程 聚合物 遗传学
作者
Renu Devi,Manish Kumar,Jagdish Singh,Jaspreet Kaur Randhawa,Navneet Kaur,Narinder Singh
出处
期刊:ACS applied nano materials [American Chemical Society]
卷期号:8 (11): 5513-5526 被引量:5
标识
DOI:10.1021/acsanm.4c07222
摘要

The demand for air filtration products has surged as air pollution worsens daily, particularly during the pandemic wave. Traditional air filters frequently require replacement because of the rapid dispersion of electrostatic charge and the buildup of harmful microorganisms. According to the World Health Organization, the majority of deaths related to air pollution are caused by noncommunicable diseases. To tackle these challenges, we have performed a centrifugal spinning experiment under controlled conditions, maintaining a temperature of 21 ± 5 °C and humidity below 36 ± 5%, with the nozzle positioned 10 cm from the collector. Nanofibrous membranes PZCR and PCCR were fabricated using an electrospinning method that offers strong antibacterial properties, effective air filtration, and the ability to be reused. These membranes consist of PAN nanofibers doped with ZnO and Cu nanoparticles and coated with a chitosan solution containing the antibacterial compound. Further, characterization was done by using FESEM, AFM, FTIR, and EDX spectroscopy. The average diameter of the PAN nanofiber before doping was 153 to 184 nm, and after doping, ZnO and Cu NPs were 225 ± 5 nm and 455 ± 5 nm, respectively. There is nearly no impact on the filtering efficiency and percentage of air resistance of the nanofiber mats, even after being treated with isopropyl alcohol, confirming compliance with ISO 16890. The membranes demonstrated a 99.9% bactericidal rate against Escherichia coli and Staphylococcus aureus bacteria, as confirmed by the ruptured bacterial cell membranes. The significant surface area relative to their volume, customizable porous structure, and ease of preparation, electrospun nanofibers make the material an ideal candidate for filtration materials, attracting significant interest in air filtration applications. Furthermore, the straining potential of these sheets remains nearly at the initial level after simple washing, outperforming commercial-grade filters.
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