Progress in the Electrochemical Reactions of Sulfonyl Compounds

Abstract Electrosynthesis has recently attracted more and more attention due to its great potential to replace chemical oxidants or reductants in molecule‐electrode electron transfer. Sulfonyl compounds such as sulfonyl hydrazides, sulfinic acids (and their salts), sulfonyl halides have been discovered as practical precursors of several radicals. As electrochemical redox reactions can provide green and efficient pathways for the activation of sulfonyl compounds, studies for electrosynthesis have rapidly increased. Several types of radicals can be generated from anodic oxidation or cathodic reduction of sulfonyl compounds and can initiate fluoroalkylation, benzenesulfonylation, cyclization or rearrangement. In this Review, we summarize the electrosynthesis developments involving sulfonyl compounds mainly in the last decade.