The Dual‐Role of Benzothiadiazole Fluorophores for Enabling Electrofluorochromic and Electrochromic Devices

Abstract Three unsymmetric fluorophores differing in their flanking electron acceptor (−NO 2 , −CN, −CHO) were investigated for their electrofluorochromism and electrochromism. The emission yield of the ‐NO 2 substituted fluorophore in the solid state was ca. 9‐fold less than its ‐CN and ‐CHO counterparts. Visible color changes of the fluorophores were observed with an applied potential. The intensity of the near‐infrared absorption at ca. 1500 nm formed upon electrochemical oxidation was contingent on the electron‐withdrawing group: 2‐fold more intense with the ‐CN substitution than its ‐H counterpart. The coloration efficiency was upwards of 655 cm 2 C −1 and the bleaching kinetics (t b ; 22 s) of the NIR band decreased according to ‐NO 2 >‐CN>‐ CHO ≈ ‐H. The electrochemically generated states could be reversibly formed during 120 min of switching the applied potential. The contrast ratio of the radical cation and the NIR absorption was near unity and 60–82 %, respectively. The photoemission intensity of the fluorophores could also be modulated with applied potentials. The collective electrochemically mediated color switching and emission intensity modulation along with their solid‐state emission demonstrate that benzothiadiazole fluorophores can play a dual role in chromic devices both as the color switching and photoemission intensity modulating material.