锑
卤化物
纳米颗粒
钙钛矿(结构)
聚合
材料科学
铅(地质)
自由基聚合
光催化
化学工程
化学
高分子化学
光化学
纳米技术
无机化学
催化作用
聚合物
有机化学
复合材料
工程类
地质学
地貌学
作者
Yifan Zhu,Jiahui Zhang
标识
DOI:10.1002/marc.202300695
摘要
Abstract Metal halide perovskites have emerged as versatile photocatalysts to convert solar energy for chemical processes. Perovskite photocatalyzed polymerization draws special attention due to its straightforward synthesis process and the ability to create advanced perovskite‐polymer nanocomposites. Herein, we employed Cs 3 Sb 2 Br 9 perovskite nanoparticles (NPs) as a lead‐free photocatalyst for light‐controlled atom transfer radical polymerization (ATRP). Cs 3 Sb 2 Br 9 NPs exhibit high reduction potential and interact with electronegative bromide initiator with Lewis acid Sb sites, enabling efficient photoinduced reduction of initiators and controlled polymerization under blue light irradiation. Methacrylate monomers with various functional groups were successfully polymerized, and the resulting polymer showcased a dispersity ( Đ ) as small as 1.27. The living nature of polymerization is confirmed by high chain end fidelity and kinetic studies. Moreover, Cs 3 Sb 2 Br 9 NPs serve as heterogeneous photocatalysts, demonstrating recyclability and reusability for up to four cycles. This work presents a promising approach to overcome the limitations of lead‐based perovskites in photoinduced controlled radical polymerization, offering a sustainable and efficient alternative for the synthesis of well‐defined polymeric materials. This article is protected by copyright. All rights reserved
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