A highly effective SERS platform formed by the fabrication of Ag@ZIF-8@Au nanoparticles for rapid detection of acetamiprid in environment

The unreasonable spraying and random migration of acetamiprid may cause pollution of crops, soil and water resources in the environment, resulting in threatening ecosystem and human health. However, the monitoring of acetamiprid using mass spectrum in the environment encounters challenges due to high-cost instruments and complex processing time. Herein, we fabricated a rapid and reliable SERS method based on Ag@ZIF-8@Au platforms for tracing acetamiprid residues in the environment. In this method, a MOF material named ZIF-8 is coated with silver nanoparticles and distributed internally between AgNPs and AuNPs to enhance Raman signal, which can enrich pesticide molecules into the hotspots area provided by noble material and helps avoid the oxidation of silver nanoparticles. High sensitivity (LOD of 9.027 × 10-10 M for acetamiprid, and SERS enhancement factor of 4.3 × 107), excellent reproducibility (6.496% or 7.198% RSD for 30 random points) and superior stability (3.127% RSD for 6 weeks) were achieved using the proposed method. Acetamiprid with concentrations from 10-4 to 10-9 M were successfully detected by SERS method. Furthermore, the linear detection models of acetamiprid in different environment matrices (lake water, tea leaves, tea garden soil, oranges and oranges orchard soil) were established and all the correlation coefficient (R2) were higher than or equal to 95%, indicating the excellent adaptability of Ag@ZIF-8@Au platform in environment. The randomly spiked concentrations of acetamiprid were also tested with good recovery values and low relative error values, further confirming the reliability of the detection method.