木质素
化学
丹宁
催化作用
氢键
分子
醛
有机化学
氢溢流
纳米颗粒
氢
吸附
化学工程
食品科学
工程类
作者
Xingjie Guo,Zhicheng Jiang,Ya Ma,Jiajun Fan,James H. Clark,Wenhua Zhang,Bi Shi
标识
DOI:10.1016/j.apcatb.2023.123175
摘要
Co-self-assembly of lignin oligomers together with other structurally similar molecules can provide composite particles with functional properties for specific applications. Herein, tannin was co-self-assembled for the first time with lignin oligomers into novel lignin–tannin particles (LxTy), induced by a dual driven force with π–π stacking interaction and hydrogen bonds. Abundant ortho-phenolic hydroxyl groups of tannin cause the efficient adsorption and partial reduction of Pd2+ ions (36.7%) by LxTy (>99%) to obtain Pd/LxTy with highly dispersed Pd nanoparticles, thereby avoiding the need for surfactants or reducing agents. Aldehyde groups of lignin-derived aldehydes could preferentially interact with phenolic hydroxyl groups on the hydrophilic shell of Pd/LxTy. Then, mitigated active hydrogen atoms on the LxTy support during the hydrogen spillover process induced a H-shift to C of −CO through a water bridge with low energy barrier and consequently selective hydrogenation to obtain lignin-derived alcohols at 30 °C.
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