电泳剂
卤化物
立体选择性
化学
烷基
联轴节(管道)
立体化学
药物化学
光化学
有机化学
材料科学
催化作用
冶金
标识
DOI:10.1016/j.checat.2022.09.041
摘要
Asymmetric C sp 3 –C sp 3 cross-electrophile coupling is a powerful tool for C–C bond formation yet still a great challenge in organic chemistry. Recently in Nature , Hyster and co-workers reported a highly stereoselective C sp 3 –C sp 3 cross-coupling of alkyl halides with nitroalkanes by photoexciting the ene-reductase (ERED)-templated charge-transfer (CT) complex. Asymmetric C sp 3 –C sp 3 cross-electrophile coupling is a powerful tool for C–C bond formation yet still a great challenge in organic chemistry. Recently in Nature , Hyster and co-workers reported a highly stereoselective C sp 3 –C sp 3 cross-coupling of alkyl halides with nitroalkanes by photoexciting the ene-reductase (ERED)-templated charge-transfer (CT) complex.
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