荧光粉
光致发光
色度
显色指数
材料科学
分析化学(期刊)
发光
离子
发光二极管
色温
光电子学
光学
化学
物理
色谱法
有机化学
作者
Yunhang Du,Xiaomeng Wang,Zeliang Qiu,Zhou Zhao,Xue Huang,Haiying Du,Wentao Zhang
标识
DOI:10.1016/j.jallcom.2021.163411
摘要
White-emitting Na5Y1-yLny(MoO4)4:Dy3+ (Ln = La, Gd) phosphors were synthesized by a sol-combustion method. The effects of Ln3+ partial introduction on the structure and photoluminescence of Na5Y1-yLny(MoO4)4:Dy3+ (Ln = La, Gd) phosphors were studied. The X-ray diffraction and chemical composition results verified the successful introduction of Dy3+, La3+ and Gd3+ into the Na5Y(MoO4)4 lattice. Under the excitation of ultraviolet at 352 nm, the as-prepared phosphors showed a white emission with characteristic emission peaks at 577 nm (yellow) and 485 nm (blue), corresponding to the 4F9/2→6H13/2 and 4F9/2→6H15/2 transitions of Dy3+ ions, respectively. By substituting Y3+ ion with La3+ and Gd3+, the photoluminescence intensity of Na5Y(MoO4)4:Dy3+ sample was obviously enhanced due to the crystal field effect surrounding the luminescence center Dy3+. The chromaticity coordinates of all phosphors were located at the white light region, and the substitution of La3+ or Gd3+ could realize a higher color rendering index of white emission. Therefore, the as-prepared white-emitting Na5Y0.90La0.06(MoO4)4:0.04Dy3+ and Na5Y0.88Gd0.08(MoO4)4:0.04Dy3+ phosphors could be used as single-component phosphor for w-LEDs application.
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