析氧
电催化剂
纳米晶材料
电化学
催化作用
材料科学
电解
钼
化学计量学
镍
化学工程
热稳定性
无机化学
电极
冶金
化学
纳米技术
物理化学
有机化学
工程类
电解质
作者
S.M. Fernández-Valverde,E. Ordóñez-Regil,Gerardo Cabañas-Moreno,O. Solorza‐Feria
出处
期刊:Journal of the Mexican chemical society
[Sociedad Quimica de Mexico, A.C.]
日期:2019-06-05
被引量:2
标识
DOI:10.29356/jmcs.v54i3.931
摘要
Nickel-molybdenum based electrolcatalysts were synthesized in organic media for the hydrogen evolution reaction (HER) and oxygen evolution reaction (OER) in alkaline media. The structure, morphology, and chemical composition of the catalysts were evaluated by XRD, SEM and AAS. Results revealed nanocristalline powder materials with Ni0.006Mo, Ni0.1Mo, and NiMo compositions. The best performance for HER, was obtained on Ni0.1Mo electrode, whereas NiMo was for the OER. Results suggest that the material with 1:1 stoichiometric ratio could be considered as a promising electrocatalyst for OER. This nanocrystalline powder is formed by Ni2Mo3O8 and a crystalline structure attributed to the possible formation of a NiMo cluster, becomes NiMoO4 .after thermal treatment at 1073K in air. The NiMo 1:1 cluster catalyst presented electrochemical stability during the OER.
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