介电谱
硫化氢
聚吡咯
化学
循环伏安法
分析物
氨
分析化学(期刊)
无机化学
电化学
等效电路
材料科学
电极
硫黄
色谱法
有机化学
物理
物理化学
电压
量子力学
作者
Adel Yavarinasab,Sajjad Janfaza,Hamed Tahmooressi,Mahan Ghazi,Nishat Tasnim,Mina Hoorfar
标识
DOI:10.1016/j.jhazmat.2021.125892
摘要
An impedance-transducer sensor was developed for in situ detection of hydrogen sulfide (H2S) and ammonia (NH3) in aqueous media. Using cyclic voltammetry (CV), polypyrrole (PPy) was deposited on the surface of the microfabricated interdigitated gold electrode. Due to the proton acid doping effect of H2S on PPy and ionic conduction of the film, the sensor showed a decreasing impedance response to H2S unlike other reducing chemicals, i.e., ammonia (NH3). The recorded faradaic data was then associated with an equivalent circuit and compared with that of NH3 to examine the selectivity of the sensor. An electrochemical impedance spectroscopy (EIS) analysis was applied to the mixture of H2S and NH3 prepared at different ratios for the concentrations ranging from 2 ppm to 20 ppm (below 2-ppm, no response was observed due to the formation of NH4HS, not sensible with PPy). The principal component analysis (PCA) was used to train a real-time prediction model for both classification (for the type of the analyte) and regression (the concentration of the analyte). The results showed the high performance of the sensor in determining individual analytes while the model was able to accurately predict the amount of H2S and NH3 in the mixture.
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