萃取(化学)
化学
乳酸
微流控
稀土
螯合作用
质子核磁共振
表征(材料科学)
分析化学(期刊)
色谱法
无机化学
材料科学
纳米技术
立体化学
矿物学
遗传学
细菌
生物
作者
Kaihua Chen,Yuan He,C. Srinivasakannan,Shiwei Li,Shaohua Yin,Jinhui Peng,Shenghui Guo,Libo Zhang
标识
DOI:10.1016/j.cej.2018.09.039
摘要
An attempt to characterize the interaction of rare earth elements with P507 in a microfluidic extraction system containing lactic acid as complexing agent is made using spectroscopic (FT-IR, UV–Vis, NMR and MS) analysis. The role of lactic acid in the extraction process is analyzed. The extraction mechanism confirmed that lactic acid does not involve in the extraction reaction. A comparative analysis of the composition of the extracts using FT-IR, UV–Vis, NMR and MS methods, indicates that the extracted complexes of rare earth ions located in the center is formed by the cation exchange process between POH and RE3+, and coordination process between PO and RE3+.
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