众包
发色团
数据科学
化学
万维网
计算机科学
光化学
出处
期刊:Science
[American Association for the Advancement of Science]
日期:2019-03-28
卷期号:363 (6434): 1411.5-1412
标识
DOI:10.1126/science.363.6434.1411-e
摘要
Organic Chemistry
Photoredox catalysis is widely used to accelerate chemical reactions by channeling the energy in visible light. However, most implementations rely on expensive chromophores to absorb light. Fu et al. now show that a pair of cheap components acting in concert can induce these reactions, despite not being strong visible absorbers individually. The combination of sodium iodide and triphenylphosphine allowed photoinduced electron transfer to catalyze a variety of alkylations.
Science , this issue p. [1429][1]
[1]: /lookup/volpage/363/1429?iss=6434
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