超级电容器
材料科学
佩多:嘘
复合数
导电聚合物
聚苯乙烯磺酸盐
纳米技术
石墨烯
聚苯胺
聚合物
电极
电化学
复合材料
化学
图层(电子)
物理化学
聚合
作者
Miao Zhang,Frédéric Héraly,Ming Yi,Jiayin Yuan
标识
DOI:10.1016/j.xcrp.2021.100449
摘要
Ti3C2Tx (MXene), a thriving member of the two-dimensional (2D) materials family, has shown increasing potential in a myriad of applications, ranging from printable electronics to energy storage and separation membranes. Nevertheless, the dilemma of its oxidative instability and the easy disintegration of its assemblies in contact with water has been restricting its real-life use. Here, we report the benefits of tartaric acid, a natural source, as a non-innocent additive in the MXene composite. In water, it can, above all, inhibit oxidation of Ti3C2Tx and hold individual components in the composite Ti3C2Tx/poly(3,4-ethylenedioxy thiophene):polystyrene sulfonate) (Ti3C2Tx/PEDOT:PSS) firmly together; equally important, it can boost 4-fold the composite's electron conductivity in comparison to the additive-free equivalent. To showcase its practical value, a tartaric-acid-treated, water-stable MXene/PEDOT:PSS conductive coating is made, which serves as electrodes for an ultrafast supercapacitor; among all 2D materials-based assemblies, the designed supercapacitor delivers, to our knowledge, the record-high performance in an alternating-current filtering application.
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