超级电容器
材料科学
电解质
假电容
假电容器
储能
密度泛函理论
功率密度
电极
电容
化学工程
纳米技术
化学
物理化学
计算化学
物理
热力学
功率(物理)
工程类
作者
Haoxiang Zhang,Le Wang,Xinxin Xing,Shuai Zhao,Kai Wang,Shengzhong Liu
标识
DOI:10.1002/adfm.202208403
摘要
Abstract Photorechargeable supercapacitors are perfect energy storage devices, particularly for solar cells that output electricity only during sunshine hours. The lower energy density of supercapacitors is due to fewer redox‐active sites, poor electrolyte accessibility at the electrodes, and charge loss during charge transfer from solar cells to the supercapacitor. Here, an electrolyte‐accessible organic–inorganic hybrid electrode with synergistic pseudocapacitance of Ti 3 C 2 T x and high theoretical specific capacity CO active centers to enhance the energy density of the supercapacitor is proposed. Density functional theory (DFT) calculations show that the covalent cross‐linking of organic molecules changes the charge density redistribution of Ti 3 C 2 T x , enhances ion absorption and storage, and increases the energy density of the supercapacitors. Based on these DFT calculation results, hybrid electrodes are successfully prepared using p‐phenylene diisocyanate to covalently cross‐link pseudocapacitors Ti 3 C 2 T x with anthraquinone such as 1‐hydroxyanthraquinone (HA) or 1‐amino‐4‐bromoanthraquinone‐2‐sodium sulfonate (ABS). The Ti 3 C 2 T x ‐HA hybrid electrodes exhibit high areal specific capacity (2532.5 mF cm −2 ), excellent ion absorption storage capability, and long‐term stability. The asymmetric supercapacitor yields a decent area specific capacity (1686.72 mF cm −2 at 0.25 mA cm −2 ) and energy density (599.72 mWh cm −2 at a power density of 200 mW cm −2 ). These high‐energy‐density supercapacitors are coupled with perovskite solar cells to prepare photorechargeable supercapacitors with fast energy storage.
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