Covalent Organic Framework Membranes: Synthesis Strategies and Separation Applications

Covalent organic frameworks (COFs) have emerged as highly promising materials for membrane separations due to their high porosity, tunable pore sizes, ordered crystalline structures, and exceptional chemical stability. With these features, COF membranes possess greater selectivity and permeability than conventional materials, making them the preferred choice in various fields, including membrane separations. Fascinating research endeavors have emerged encompassing fabrication strategies for COF-based membranes and their diverse separation applications. Hence, this review summarizes the latest advancements in COF synthesis, including COF powders and continuous COF-based membranes and their applications in separation membranes. Special consideration was given to regulation strategies for the performance optimization of COF membranes in separation applications, such as pore size, hydrophilicity/hydrophobicity, surface charge, crystallinity, and stability. Furthermore, applications of COF membranes in water treatment, metal ion separation, organic solvent nanofiltration, and gas separation are comprehensively reviewed. Finally, the research results and future prospects for the development of COF membranes are discussed. Future research may be focused on the following key directions: (1) single-crystal COF fabrication, (2) cost-effective membrane preparation, (3) subnanometer pore engineering, (4) advanced characterization techniques, and (5) AI-assisted development.