硅醇
光致发光
杂质
钙钛矿(结构)
纳米晶
配体(生物化学)
材料科学
相(物质)
化学工程
光化学
无机化学
化学
光电子学
纳米技术
催化作用
结晶学
有机化学
生物化学
受体
工程类
作者
Yipeng Huang,Fangyuan Lin,Feiming Li,Jinwen Jin,Zhiyong Guo,Dongjie Tian,Rong‐Jun Xie,Xi Chen
标识
DOI:10.1002/anie.202402520
摘要
The detriments of intrinsic silanol groups in mesoporous silica to the photoluminescence (PL) of lead halide perovskite nanocrystals (LHP NCs) confined in the template have never been realized and clearly elucidated. Here, we disclose that the silanol induced Cs+ and Br‐ deficiencies prompt the generation of traps and CsPb2Br5 impurities. The temperature dependent PL spectra verify the higher energetic barrier of trap states in CsPbBr3 NCs confined in silanol‐rich mesoporous silica. Femtosecond transient absorption spectra reveal the trapped state mediated broadband photoinduced absorption and long‐lived decay pathway of CsPbBr3 NCs in silanol‐rich templates. Remarkable improvement (maximal 160‐fold) in PL quantum yields is realized by simple silanol elimination. This work demonstrates the detrimental effects of silanol sites on the PL properties of LHP NCs impregnated in mesoporous silica, and provides new perspective for ligand‐free synthesis of high‐quality LHP NCs in mesoporous templates by facile impregnation for practical applications.
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