水解
试剂
溶解度
氟化物
化学
核化学
催化作用
铜
矿物学
无机化学
有机化学
作者
Masakatsu Shibasaki,Motomu Kanai,Kane A.C. Bastick,Allan J. B. Watson
标识
DOI:10.1002/047084289x.rn00744.pub2
摘要
[11113-59-0] CuF (MW 82.54) InChI = 1S/Cu.FH/h;1H/q+1;/p-1 InChIKey = BMRUOURRLCCWHB-UHFFFAOYSA-M (reagent used as a fluoride source; useful catalyst for a variety of synthetic conversions; in the absence of ligands such as phosphines CuF is unknown) [7789-19-7] CuF2 (MW 101.54) InChI = 1S/Cu.2FH/h;2*1H/q+2;;/p-2 InChIKey = GWFAVIIMQDUCRA-UHFFFAOYSA-L Physical Data: mp ∼785 °C (N2 atmosphere); d 4.85 g cm−1. Solubility: soluble in H2O (20 °C) = 4.7 g/100 mL, hydrolyzed to CuFOH in hot H2O. [13454-88-1] CuF2·2H2O (MW 118.57) InChI = 1S/Cu.2FH.2H2O/h;2*1H;2*1H2/q+2;;;;/p-2 InChIKey = CTRICEWDSISGPV-UHFFFAOYSA-L Physical Data: dp >130 °C; d 2.93 g cm−1. Solubility: soluble in H2O = 4.7 g/100 mL, hydrolyzed to CuFOH in hot H2O. Form Supplied in: blue powder; widely available.
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