环己酮
碳纤维
喷气燃料
烷基
钯
喷射(流体)
联轴节(管道)
材料科学
化学
有机化学
催化作用
热力学
物理
冶金
复合数
复合材料
作者
Matea Bačić,Judit Oliver–Meseguer,Antonio Leyva−Pérez
标识
DOI:10.1016/j.apcata.2024.119632
摘要
The cyclohexanone / cyclohexanol mixture (KA oil) is one of the most produced C6 chemicals worldwide, derived from renewable sources if desired; however, the use of KA oil as a precursor for zero net emission fuels has not been studied in-depth yet, as far as we know. We show here that KA oil is converted to an aromatic-free product mixture compatible with the composition of jet fuels after a series of carbon-carbon coupling reactions, of either KA oil with itself or with bioderived alcohols, in the presence of a commercially available solid-supported palladium on carbon catalyst under basic conditions (KOH). Water is the only by-product of the reaction, and phosphines can be used as ligands to variate the final product composition.
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