分离器(采油)
多孔性
锌
材料科学
电池(电)
超级电容器
化学工程
冶金
工程类
化学
复合材料
电化学
电极
物理
物理化学
热力学
功率(物理)
作者
Tian Zhao,Jian Yu,Pengcheng Xiao,Saiqun Nie,Shilin Peng,Jiayao Chen,Fuli Luo,Christoph Janiak,Yi Chen
出处
期刊:Chemistry
[Multidisciplinary Digital Publishing Institute]
日期:2024-10-31
卷期号:6 (6): 1363-1373
标识
DOI:10.3390/chemistry6060080
摘要
This study successfully prepared a hierarchically porous ZIF-67 (H-ZIF-67) by incorporating the polyvinylpyrrolidone (PVP) at room temperature. Compared to standard control ZIF-67 (C-ZIF-67) with a yield of 81% and a BET specific surface area of 1228 m2·g−1, the H-ZIF-67 not only exhibited improved crystallinity and pore structure but also achieved a yield of up to 93% and a BET specific surface area of 1457 m2·g−1. Due to its hierarchically porous structure, H-ZIF-67 demonstrated excellent adsorption capacity and efficiency for methylene orange (MO). Additionally, the composite separator created by combining H-ZIF-67 with nanocellulose (CNF) exhibited remarkable uniformity and dispersion in zinc batteries. In comparison to a conventional CNF separator, the porous structure and high specific surface area of H-ZIF-67 significantly enhanced its electrolyte wettability and Zn2+ transport rates. Its abundant Lewis acid sites effectively promoted the uniform deposition of Zn2+, thereby suppressing the formation of zinc dendrites and improving the cycling and safety performance of zinc-ion batteries. Experimental results indicate that the ion conductivity of the membrane was 4.31 mS·cm−1, the electrolyte absorption rate was 316%, and it could cycle stable for over 4000 h at a current density of 1 mA·cm−2 with a discharge capacity of 1 mAh·cm−2. This achievement will open up new avenues for the preparation and application of ZIF-67 composite separators in aqueous zinc-ion batteries.
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