Miracle in “White”:Hexagonal Boron Nitride

Abstract The exploration of 2D materials has captured significant attention due to their unique performances, notably focusing on graphene and hexagonal boron nitride (h‐BN). Characterized by closely resembling atomic structures arranged in a honeycomb lattice, both graphene and h‐BN share comparable traits, including exceptional thermal conductivity, impressive carrier mobility, and robust pi–pi interactions with organic molecules. Notably, h‐BN has been extensively examined for its exceptional electrical insulating properties, inert passivation capabilities, and provision of an ideal ultraflat surface devoid of dangling bonds. These distinct attributes, contrasting with those of h‐BN, such as its conductive versus insulating behavior, active versus inert nature, and absence of dangling surface bonds versus absorbent tendencies, render it a compelling material with broad application potential. Moreover, the unity of such contradictions endows h‐BN with intriguing possibilities for unique applications in specific contexts. This review aims to underscore these key attributes and elucidate the intriguing contradictions inherent in current investigations of h‐BN, fostering significant insights into the understanding of material properties.