化学
催化作用
转移加氢
金属
传输(计算)
物理化学
有机化学
钌
计算机科学
并行计算
作者
Jeffrey A. Farrell,Zachariah M. Heiden,Douglas W. Stephan
出处
期刊:Organometallics
[American Chemical Society]
日期:2011-08-02
卷期号:30 (17): 4497-4500
被引量:100
摘要
The activation of amines by B(C6F5)3 is shown to effect the catalytic racemization of a chiral amine. Extending this strategy to a bimolecular process, catalytic transfer hydrogenation of imines, enamines, and N-heterocycles is demonstrated using iPr2NH as the source of hydrogen and a catalytic amount of the Lewis acid B(C6F5)3.
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