溴
卤化
吸附
化学
卤化物
锆
吸附剂
无机化学
化学工程
有机化学
工程类
作者
Jiandong Pang,Shuai Yuan,Dong‐Ying Du,Christina Lollar,Liangliang Zhang,Mingyan Wu,Daqiang Yuan,Maochun Hong
标识
DOI:10.1002/anie.201709186
摘要
Abstract A series of flexible MOFs (PCN‐605, PCN‐606, and PCN‐700) are synthesized and applied to reversible bromine encapsulation and release. The chemical stability of these Zr‐MOFs ensures the framework's integrity during the bromine adsorption, while the framework's flexibility allows for structural adaptation upon bromine uptake to afford stronger host–guest interactions and therefore higher bromine adsorption capacities. The flexible MOFs act as bromine‐nanocontainers which elongate the storage time of volatile halides under ambient conditions. Furthermore, the bromine pre‐adsorbed flexible MOFs can be used as generic bromine sources for bromination reactions giving improved yields and selectivities under ambient conditions when compared with liquid bromine.
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