试剂
化学
氟
功能群
组合化学
反应条件
有机化学
催化作用
聚合物
作者
Xing Zheng,Xingang Zhang,Yuyan Ren
出处
期刊:Synlett
[Thieme Medical Publishers (Germany)]
日期:2018-03-07
卷期号:29 (08): 1028-1032
被引量:25
标识
DOI:10.1055/s-0036-1591944
摘要
Bromotrifluoromethane (CF3Br) is a simple, inexpensive and abundant industrial material employed as a trifluoromethylating reagent. However, only limited strategies using CF3Br as a fluorine source are reported. Herein, we describe a visible-light-induced hydrotrifluoromethylation of alkenes and alkynes with CF3Br. The reaction proceeds under mild conditions with good functional group tolerance, providing a new route for the application of BrCF3 in organic synthesis.
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