罗丹明6G
材料科学
石墨烯
拉曼散射
纳米棒
基质(水族馆)
拉曼光谱
光催化
吸附
氧化物
纳米技术
化学工程
光电子学
分子
光学
化学
催化作用
有机化学
工程类
冶金
地质学
物理
海洋学
作者
Yanfen Wang,Miao Zhang,Hai Yu,Yong Zuo,Juan Gao,Gang He
标识
DOI:10.1016/j.apcatb.2019.03.084
摘要
A novel graphene oxide/TiO2 nanorod array (GO/TNR) decorated with Ag nanoparticles (NPs) is successfully prepared as a photocatalyst and a surface-enhanced Raman scattering (SERS) substrate for organic molecule detection. The as-obtained Ag/GO/TNR sample exhibited a large specific surface area and high adsorption capacity toward Rhodamine 6G (R6G) molecules. Moreover, the GO interlayer with suitable content had a significant effect on the absorption intensity of light and Raman signals for the Ag/GO/TNR substrate. For R6G as probe molecules, the Ag/GO/TNR substrate with 5 min of GO-deposition achieved a lower detection limit of 1.0 × 10−12 M and an improved enhancement factor (EF) of 5.86 × 105 as compared to other films. Furthermore, the relative standard deviation (RSD) value of the Raman vibration at 1650 cm−1 cm was approximately 8.71%, and the good uniformity remained. Using Xenon lamp irradiation, the outstanding photocatalytic ability endowed the substrate with good self-cleaning and reusable properties. Based on the above results, a synergistic effect of three components (Ag NPs, GO interlayer, and TNR) is proposed to produce an excellent SERS performance, namely, a large adhesion area, the interaction of excited photons, and high-density hotspots in the active substrate.
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