镝
奋乃静
再现性
检出限
材料科学
选择性
精神分裂症(面向对象编程)
电化学
电极
重复性
化学
色谱法
无机化学
药理学
医学
有机化学
精神科
物理化学
催化作用
作者
Venkatachalam Vinothkumar,Rajalakshmi Sakthivel,Shen-Ming Chen
标识
DOI:10.1016/j.mtchem.2022.100883
摘要
Currently, perphenazine (PPZ) is widely used to treat the symptoms of schizophrenia, namely, a mental illness that reasons strong or improper emotions, loss of interest in life, and disturbed or abnormal thinking. In addition, the PPZ is exploited to control acute nausea and vomiting in adults, and it acts by reducing unusual excitement in the brain. Accordingly, we report a novel dysprosium nickelate (DyNiO3)-modified electrodes were used to detect PPZ. The DyNiO3 nanospheres were synthesized via the coprecipitation method. The excellent electron transport behavior and electrocatalytic activity of DyNiO3-modified screen-printed electrode (SPCE) were used in the electro-oxidation of PPZ. The constructed DyNiO3-500°C/SPCE sensor has a broad linear range and a low detection limit of 0.04–761.6 μM and 0.006 μM, respectively. The resultant-modified sensor demonstrates appreciable reproducibility, selectivity, repeatability, cyclic, and storage stability toward PPZ detection. The practicability of the reported fabricated electrode was investigated in human biological samples (urine and serum) spiked with PPZ, and the correlated recoveries were acceptable.
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