材料科学
聚氨酯
烧焦
复合材料
三聚氰胺
热稳定性
消防安全
傅里叶变换红外光谱
阻燃剂
燃烧
异氰酸酯
化学工程
化学
有机化学
管理
经济
工程类
作者
Bing Zhang,Zhaohe Feng,Yadong Yang,Xiangrong Xu,Depeng Chen,Xinjie Huang,Chunlin Li,Xiuyu Liu,Gang Tang
标识
DOI:10.1080/14658011.2021.2024647
摘要
Biomass melamine phytates (MEL-PA) flame retardant was fabricated by a facile method, and MEL-PA was used to prepare a series of RPUF/MEL-PA composites by one-step water-blown technology. Compared with that of pure RPUF, the degradation rate of RPUF/MEL-PA composites decreased at a high temperature, and the char residues increased significantly, indicating that the thermal stability of the composites is improved. The smoke density test and TG-FTIR revealed that MEL-PA can significantly inhibit the release of smoke, flammable gases (e.g. esters and hydrocarbons) and toxic and harmful gases (e.g. isocyanate compounds, aromatic compounds and CO), implying significant enhancement of the fire safety of RPUF/MEL-PA composites. SEM, Raman spectra and FTIR spectroscopy were employed to investigate char residues of the composites. MEL-PA was found to catalyse the RPUF matrix to form compact char residues with a high graphitisation degree, significantly inhibiting heat and mass transmission processes during combustion.
科研通智能强力驱动
Strongly Powered by AbleSci AI