化学
激进的
硅烷化
替代(逻辑)
吡那考
药物化学
自由基环化
有机化学
催化作用
计算机科学
程序设计语言
作者
Hongyan Lan,Xiangyu Huo,Ying‐Gang Jia,Derong Wang
标识
DOI:10.1021/acs.orglett.3c04085
摘要
A novel strategy was developed to generate silyl radicals from silylboronic pinacol esters (SPEs) through nucleohomolytic substitution of boron with aminyl radicals. We successfully applied this strategy to obtain diverse organosilicon compounds using SPEs and N-nitrosamines under photoirradiation without any catalyst. The ability to access silyl radicals offers a new perspective for chemists to rapidly construct Si–X bonds.
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