Measurements of double differential cross sections for electron emission at zero degrees arising from collisions of 100 keV protons with H 2 and He have been carried out. Calculations based on a continuum-distorted-wave eikonal-initial-state model have also been carried out and shown to provide a good description of the measurements. In addition, classical-trajectory Monte Carlo calculations have been employed to illustrate the evolution of electron emission at different times during the collision. The present measurements, which use a well defined gas target, provide no evidence of the existence of a significant saddle-point ionization mechanism at the energy considered.