阳极
锂(药物)
电解质
化学工程
成核
化学
容量损失
材料科学
图层(电子)
阴极
枝晶(数学)
碱金属
纳米技术
电极
物理化学
有机化学
内分泌学
工程类
医学
数学
几何学
作者
Song Li,Xianshu Wang,Bing Han,Chen Lai,Peiran Shi,Jiabin Ma,Shu Wei Wang,LiHan Zhang,Qi Liu,Yonghong Deng,Yan-Bing He,Quan-Hong Yang
出处
期刊:Small
[Wiley]
日期:2021-12-09
卷期号:18 (8): 2106427-2106427
被引量:9
标识
DOI:10.1002/smll.202106427
摘要
Lithium (Li) metal batteries (LMBs) face huge challenges to achieve long cycling life at wide temperature range owing to the severe dendrite growth at subambient temperature and the intense side reactions with electrolyte at high temperature. Herein, an ultrathin LiBO2 layer with an extremely high Young's modulus of 8.0 GPa is constructed on Li anode via an in situ reaction between Li metal and 4,4,5,5-tetramethyl-1,3,2-dioxa-borolane (TDB) to form LiBO2 @Li anode, which presents two times higher exchange current density than pristine Li anode. The LiBO2 layer presents a strong absorption to Li ions and greatly improves the interfacial dynamics of Li-ion migration, which induces homogenous lithium nucleation and deposition to form a dense lithium layer. Consequently, the Li dendrite growth during cycling at subambient temperature and the side reactions with electrolyte at high temperature are simultaneously suppressed. The LiBO2 @Li/LiNi0.8 Co0.1 Mn0.1 O2 (NCM811) full batteries with limited Li capacity and high cathode mass loading of 9.9 mg cm-2 can steadily cycle for 300 cycles with a capacity retention of 86.6%. The LiBO2 @Li/NCM811 full batteries and LiBO2 @Li/LiBO2 @Li symmetric batteries also present excellent cycling performance at both -20 and 60 °C. This work develops a strategy to achieve outstanding performance of LMBs at wide working temperature-range.
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