Intrinsic high-k–low-loss dielectric polyimides containing ortho-position aromatic nitrile moieties: reconsideration on Clausius–Mossotti equation

Intrinsic high-k–low-loss dielectric polyimides containing ortho-position aromatic nitrile moieties were synthesized. 2CN-BTDA shows a D_k of 4.80, D_f of 1.57 × 10⁻³ at 1 kHz (25 °C), E_B of 219.4 kV mm⁻¹ with energy density of 1.023 J cm⁻³ and T_g of 325 °C.