Plasma‐Strengthened Lithiophilicity of Copper Oxide Nanosheet–Decorated Cu Foil for Stable Lithium Metal Anode

Abstract Lithium metal is the most ideal anode for next‐generation lithium‐ion batteries. However, the formation of lithium dendrites and the continuous consumption of electrolyte during cycling lead to a serious safety problems. Developing stable lithium metal anode with uniform lithium deposition is highly desirable. Herein, a nitrogen plasma strengthening strategy is proposed for copper oxide nanosheet–decorated Cu foil as an advanced current collector, and deep insights into the plasma regulating mechanism are elaborated. The plasma‐treated electrode can maintain a high coulombic efficiency of 99.6% for 500 cycles. The symmetric cell using the lithium‐plated electrode can be cycled for more than 600 h with a low‐voltage hysteresis (23.1 mV), which is much better than those of electrodes without plasma treatment. It is well confirmed that this plasma‐induced nitrogen doping method can provide sufficient active sites for lithium nucleation to enhance the stability of lithium deposition on copper oxide nanosheets decorated on Cu foil and improve the electrical conductivity to greatly reduce the overpotential of the lithium nucleation, which can be extended to other modified current collectors for stable lithium metal anode.