材料科学
阴极
钾
烧结
过渡金属
氧化物
水分
金属
化学工程
冶金
复合材料
物理化学
有机化学
催化作用
工程类
化学
作者
Yuqing Cai,Xu Zeng,Dawei Pang,Yuyang Gu,Juquan Qi,Titus Masese,Fangfei Chang,Yonghua Li,Shi Wang,Ziquan Li,Zhen Dong Huang,Titus Masese
出处
期刊:Materialia
[Elsevier]
日期:2023-03-01
卷期号:27: 101674-101674
被引量:2
标识
DOI:10.1016/j.mtla.2023.101674
摘要
Layered transition metal oxides are deemed the most promising cathode materials for potassium-ion batteries owing to their high energy density and scalable design. However, their inherent moisture sensitivity thwarts their potential commercial realization. Herein, we show the efficacy of plasma-enhanced sintering technique in enhancing the environmental stability of K0.6Ni0.2Co0.3Mn0.5O2 layered oxide. The attained K0.6Ni0.2Co0.3Mn0.5O2 microspheres manifest a potassium-deficient surface layer that significantly suppresses surface hygroscopicity. Consequently, K0.6Ni0.2Co0.3Mn0.5O2 can be kept and handled in ambient air condition, while yet achieve competitive potassium-ion storage performance compared with other reported layered cathode materials with similar composition and microstructures. Overall, this work accentuates plasma-enhanced sintering techniques as an effective strategy to circumvent the moisture sensitivity of potassium-containing layered metal oxides, leverageable to hygroscopic layered metal oxides for other energy storage systems.
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