Mid-Infrared Optical Force Chromatography of Microspheres Containing Siloxane Bonds

Recent interest in particle sorting using optical forces has grown due to its ability to separate micro- and nanomaterials based on their optical properties. Here, we present a mid-infrared optical force manipulation technique that enables precise sorting of microspheres based on their molecular vibrational properties using a mid-infrared quantum cascade laser. Utilizing the optical pushing force driven by a 9.3 μm mid-infrared evanescent field generated on a prism through total internal reflection, a variety of microspheres, including those composed of Si–O–Si bonds, can be separated in accordance with their absorbance values at 9.3 μm. The experimental results are in good agreement with the optical force calculations using finite-difference time-domain simulation. Thus, each microsphere’s displacement and velocity can be predicted from the absorbance value; conversely, the optical properties (e.g., absorbance and complex refractive index in the mid-infrared region) of individual microspheres can be estimated by monitoring their velocity.