聚合物
叠氮化物
共轭微孔聚合物
材料科学
组合化学
环加成
共轭体系
作者
Jong In Park,June Young Jang,Yoon-Joo Ko,Sang Moon Lee,Hae Jin Kim,Hye-Young Jang,Kyoung Chul Ko,Seung Uk Son
标识
DOI:10.1002/asia.202100323
摘要
This work shows that hollow microporous organic polymer (H-MOP-A) with activated internal alkynes as IR probes can be prepared by template synthesis based on acyl Sonogashira-Hagihara coupling at room temperature. The H-MOP-A is a versatile platform in the main chain PSM based on nonradical thiol-yne click reaction. Moreover, an IR peak of internal alkynes in the H-MOP-A is very intense and could be utilized in the monitoring of thiol-yne click-based main chain PSM. The functionalized H-MOP-A with carboxylic acids (H-MOP-CA) showed efficient adsorption toward Ag + ions. The resultant H-MOP-CA-Ag showed excellent performance in the CO 2 fixation to α-alkylidene cyclic compounds.
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