假电容器
材料科学
假电容
石墨烯
电容
超级电容器
氧化物
电化学
金属有机骨架
纳米技术
制作
化学工程
多孔性
电极
冶金
复合材料
有机化学
吸附
物理化学
化学
病理
工程类
替代医学
医学
作者
Yingjie Zhou,Zemin Mao,Wei Wang,Zekun Yang,Xiang Liu
标识
DOI:10.1021/acsami.6b10640
摘要
This paper reports a series of novel Ni-based metal–organic framework (Ni–MOFs) prepared by a facile solvothermal process. The synthetic conditions have great effects on the Ni–MOFs morphologies, porous textures, and their electrochemical performance. Improved capacitance performance was successfully realized by the in-situ hybrid of Ni–MOFs with graphene oxide (GO) nanosheets (Ni–MOFs@GO). The pseudocapacitance of ca. 1457.7 F/g for Ni–MOFs obtained at 180 °C with HCl as the modulator was elevated to ca. 2192.4 F/g at a current density of 1 A/g for the Ni–MOFs@GO with GO contents of 3 wt %. Additionally, the capacitance retention was also promoted from ca. 83.5% to 85.1% of its original capacitance at 10 A/g even after 3000 cycles accordingly. These outstanding electrochemical properties of Ni-based MOF materials may be related to their inherent characteristics, such as the unique flower-like architecture and fascinating synergetic effect between the Ni–MOFs and the GO nanosheets.
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