生物炭
浸出(土壤学)
化学
环境化学
吸附
修正案
土壤水分
吸附
土壤科学
有机化学
地质学
政治学
热解
法学
作者
Yutao Peng,Baige Zhang,Chung‐Yu Guan,Xiaoqian Jiang,Jian Tan,Xiaoyun Li
标识
DOI:10.1016/j.scitotenv.2022.157037
摘要
Biochar (BC) as a increasing widely adopted soil amendments showed potential threat to soil P leaching, but the relevant mechanisms were not clear enough and relevant strategy should be proposed to address the P leaching induced by BC application. In this study, effects of ordinary corn straw BC, and a fabricated Mg/Al-LDHs modified biochar (LBC) on soil P availability, adsorption, fraction and mobility were compared and investigated by conducting the column and incubation experiments at biochar to soil rate of 1 %, 2 % and 4 % (w/w). Chemical sequential extraction methods and various solid-state method (i.e., three-dimensional excitation emission matrix (EEM), x-ray diffraction (XRD), scanning electron micrograph (SEM) and P K-edge X-ray absorption near edge structure (XANES)) were utilized to give deep insights into the P mobilization and immobilization mechanisms by respectively applying the BC and LBC. Results of incubation experiments showed that applying the LBC reduced the labile P with significant CaP transformation to Al-retained P, while ordinary BC promoted the Fe/Al-P transformation to labile dibasic calcium phosphate and monobasic calcium phosphate evidenced by the EEM analysis, in-situ XANES investigation and chemical sequential extraction methods. Results of phosphatase and microbial analyses indicated that the decreased labile P after 30 days' incubation and the mitigated P leaching in LBC treatment were dominantly ascribed to abiotic processes of inorganic P transformation and (de)sorption. This research gave deep insights into abiotic and biotic processes of ordinary biochar promoting soil P leaching, and important implications for applying engineered biochar in reducing P leaching and improving soil productivity.
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