Judicious Design and Rapid Manufacturing of a Flexible, Mechanically Resistant Liquid‐Like Coating with Strong Bonding and Antifouling Abilities

Fluorine-free liquid-repellent coatings have been highly demanded for a variety of applications. However, rapid formation of coatings possessing outstanding oil repellency and strong bonding ability as well as good mechanical strength (e.g., bendability, impact resistance, and scratch resistance) remains a grand challenge. Herein, a robust strategy to rapidly create fluorine-free oil-repellent coatings in only 30 s via rational design of a semi-interpenetrating polymer network structure is reported. The resulting coating manifests strong bonding capability both in air and underwater. More importantly, it not only provides unprecedented oil repellency, even to high-viscosity crude oil, but also achieves both excellent bendability and hardness. This simple yet effective design strategy opens up a new avenue to manufacture multifunctional materials and devices with desirable features and structural complexities for applications in sustainable antifouling, drag reduction, nondestructive transportation, liquid collection, and biomedicine, among other areas.