聚丙烯酰胺
肿胀 的
材料科学
水泥
高吸水性高分子
抗压强度
复合材料
固化(化学)
氢氧化钙
聚合物
自愈水凝胶
化学工程
高分子化学
工程类
作者
Cole R. Davis,Baishakhi Bose,Alejandro M. Alcaraz,Carlos J. Martinez,Kendra A. Erk
出处
期刊:Rilem bookseries
日期:2019-11-25
被引量:1
标识
DOI:10.1007/978-3-030-33342-3_3
摘要
Polyacrylamide (PAM) superabsorbent polymer microspheres were synthesized for use as internal curing agents in low water-to-cement ratio mixtures. An increase in PAM swelling capacity in pore solutions was achieved by reducing the crosslinking density during synthesis: 5.1 g/g swelling was observed for 2 wt.% crosslinker and 20.6 g/g for 0.5 wt.% crosslinker. Capillary micromechanical experiments showed that a reduction in crosslinking density decreased the PAM elastic modulus from 1100 ± 310 kPa to 110 ± 15 kPa. Yet all PAM maintained mechanical integrity when mixed with cement and cured under a compressive load. SEM analysis showed hydrated product formation within cement voids left behind by dehydrated PAM. PAM with reduced crosslinking densities resulted in a 26 ± 7.3% increase in hydrated product formation within these voids. Cement paste density and compressive strength was not compromised by the addition of PAM.
科研通智能强力驱动
Strongly Powered by AbleSci AI