36‐Nuclearity Organophosphonate‐Functionalized Polyoxomolybdates: Synthesis, Characterization and Selective Catalytic Oxidation of Sulfides

The crown-shaped 36-molybdate cluster organophosphonate-functionalized polyoxomolybdates with the highest nuclearity in organophosphonate-based polyoxometalate chemistry, (NH₄ )₁₉ Na₇ H₁₀ [Cu(H₂ O)TeMo₆ O₂₁ {N(CH₂ PO₃ )₃ }]₆ ⋅31 H₂ O, has been reported for the first time. The synthesized 36-molybdate cluster was characterized by routine techniques and tested as a heterogeneous catalyst for selective oxidation of sulfides with impressive catalytic and selective performances after heat treatment. High efficiency (TON=15333) was achieved in the selective oxidation of sulfides to sulfoxides, caused by the synergic effect between copper and polyoxomolybdates and the generation of the cuprous species during the heat treatment.